AskDefine | Define elastomer

Dictionary Definition

elastomer n : any of various elastic materials that resemble rubber (resumes its original shape when a deforming force is removed)

User Contributed Dictionary

English

Noun

  1. any polymer having the elastic properties of rubber

Translations

Extensive Definition

An elastomer is a polymer with the property of elasticity. The term, which is derived from elastic polymer, is often used interchangeably with the term rubber, and is preferred when referring to vulcanisates. Each of the monomers which link to form the polymer is usually made of carbon, hydrogen, oxygen and/or silicon. Elastomers are amorphous polymers existing above their glass transition temperature, so that considerable segmental motion is possible. At ambient temperatures rubbers are thus relatively soft (E~3MPa) and deformable. Their primary uses are for seals, adhesives and molded flexible parts.

Background

Elastomers are usually thermosets (requiring vulcanization) but may also be thermoplastic (see thermoplastic elastomer). The long polymer chains cross-link during curing. The molecular structure of elastomers can be imagined as a 'spaghetti and meatball' structure, with the meatballs signifying cross-links. The elasticity is derived from the ability of the long chains to reconfigure themselves to distribute an applied stress. The covalent cross-linkages ensure that the elastomer will return to its original configuration when the stress is removed. As a result of this extreme flexibility, elastomers can reversibly extend from 5-700%, depending on the specific material. Without the cross-linkages or with short, uneasily reconfigured chains, the applied stress would result in a permanent deformation.
Temperature effects are also present in the demonstrated elasticity of a polymer. Elastomers that have cooled to a glassy or crystalline phase will have less mobile chains, and consequentially less elasticity, than those manipulated at temperatures higher than the glass transition temperature of the polymer.
It is also possible for a polymer to exhibit elasticity that is not due to covalent cross-links, but instead for thermodynamic reasons.

Mathematic justifications

Using the laws of thermodynamics, stress definitions and polymer characteristics (complete derivation in [1], pages103-105), we find ideal stress behavior:
\sigma\ = n k T [ \lambda\ _ 1 ^ 2 + \lambda\ _ 1 ^ ]
where n is the number of chain segments per unit volume, k is Boltzmann's Constant, T is temperature, and \lambda\ _ 1 is distortion in the 1 direction.
These findings are accurate for values of up to approximately 400% strain. At this point, alignment between stretched chains begins to result in crystallization from noncovalent bonding.
While Young's Modulus does not exist for elastomers due to the nonlinear nature of the stress-strain relationship, a "secant modulus" can be found at a particular strain.

Examples of elastomers

Unsaturated rubbers that can be cured by sulfur vulcanization: (Note that unsaturated rubbers can also be cured by non-sulfur vulcanization if desired).
Saturated Rubbers that cannot be cured by sulfur vulcanization:
Various other types of elastomers:

References

  • Treloar L.R.G., The Physics of Rubber Elasticity, Oxford University Press, 1975. ISBN 0-19-85027-9.
  • Meyers and Chawla. Mechanical Behaviors of Materials, Prentice Hall, Inc. (Pearson Education) 1999.
  • Budinski, Kenneth G., Budinski, Michael K., Engineering Materials: Properties and Selection, 7th Ed, 2002. ISBN 0-13-030533-2.
elastomer in Arabic: وحدة مرنة
elastomer in German: Elastomer
elastomer in Spanish: Elastómero
elastomer in Esperanto: Elastomero
elastomer in Persian: الاستومر
elastomer in French: Élastomère
elastomer in Italian: Elastomero
elastomer in Dutch: Elastomeer
elastomer in Polish: Elastomery
elastomer in Portuguese: Elastômero
elastomer in Russian: Эластомер
elastomer in Slovenian: Elastomer
elastomer in Finnish: Elastomeeri
elastomer in Swedish: Elastomer
elastomer in Ukrainian: Еластомери
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